Crystal structure of tris

Authors

Colin T. Hartgerink, Calvin University
Richard J. Staples, Michigan State University
Carolyn E. Anderson, Calvin University

Document Type

Article

Publication Title

Acta Crystallographica Section E: Crystallographic Communications

Abstract

The title ketenyl­idene, [Au3(C2O)(C26H35O2P)3](C2F6NO4S2), was obtained upon exposure of [2-(di­cyclo­hexyl­phosphino)-2′,6′-dimeth­oxy-1,1′-biphen­yl]gold(I) bis­(tri­fluoro­methane­sulfon­yl)imide to acetic anhydride at elevated temperature. The ketenyl­idene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenyl­idene with atomic distances indicative of bonding inter­action between the gold atoms.

First Page

537

Last Page

541

DOI

10.1107/S2056989021003844

Publication Date

5-1-2021

Recommended Citation

Hartgerink, Colin T.; Staples, Richard J.; and Anderson, Carolyn E., "Crystal structure of tris" (2021). University Faculty Publications and Creative Works. 127.
https://digitalcommons.calvin.edu/calvin_facultypubs/127